Corrosion inhibition potentials of Roselle (Hibiscus sabdariffa) in tetraoxosulphate (VI) acid solution

Authors

  • Emmanuel Elachi Department of Mechanical Engineering, Taraba State University, Jalingo, Taraba State, Nigeria https://orcid.org/0000-0002-1155-7272
  • Austine Justine Department of Mechanical Engineering Taraba State University, Jalingo, Taraba State, Nigeria
  • Micheal Paul Department of Mechanical Engineering Taraba State University, Jalingo, Taraba State, Nigeria
  • Keneath D. Yusuf Department of Mechanical Engineering Taraba State University, Jalingo, Taraba State, Nigeria
  • Aliyu B. Madugu Department of Mechanical Engineering Taraba State University, Jalingo, Taraba State, Nigeria

Keywords:

Corrosion, Inhibition, Roselle (Hibiscus sabdariffa), Inhibition efficiency, Tetraoxoxulphate (VI) acid

Abstract

The harmful effects of chemical based corrosion inhibitors on man and the ecosystem prompted the search for alternatives that are non hazardous to the environment.Therefore, the corrosion inhibition potentials of the leaves and flowers of the green variety of Roselle (Hibiscus sabdariffa) were evaluated.This was undertaken mainly to investigate the effectiveness of the leaves and flowers of Roselle in mitigating the corrosion of mild steel in acidic medium. The gravimetric method of corrosion measurement was used to evaluate the corrosion inhibition potentials of the plant parts. The results showed that the leaves and flowers of the plant can effectively be used to mitigate the corrosion of metals in acidic medium. The maximum inhibition efficiencies of the leaves and flower extracts of the plant were 27.94 % and 22.81 % respectively. The leaves and flowers of the plant were more efficient on the first eight days of application.

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References

P. C. Okafor, V. I. Osabor and E. E. Ebenso, “Eco-friendly Corrosion Inhibitors: Inhibitive Action of Ethanol Extracts of Garcinia kola for the Corrosion of Mild Steel in H2SO4 Solution,” Pigment and Resin Technology, vol. 36, pp. 299-305, 2007.

S. Rajendran, A. J. Amalray, M. J. Joice, N. Anthony, D. C. Trived and M. Sundaravadivelu, “Corrosion Inhibition by the Caffeine-Zn System,” Corrosion Reviews, vol. 22, pp. 233-248, 2004.

P. C. Okafor, E. E. Ebenso, and U. J. Ekpe, “Azadirachta indica Extracts as Corrosion Inhibitor for Mild Steel in Acidic Medium,” International Journal of Electrochemical Science, vol. 5 pp. 978-993, 2010

O. Olawale, B. T. Ogunsemi, O.O. Agboola, M. B. Ake, and G. O. Jawando, “Inhibition Effect of Orange Seed Extract on Aluminum Corrosion in 1 M Hydrochloric Acid Solution,” International Journal of Mechanical Engineering and Technology, vol. 9, pp. 282-287, 2018.

D. W. Oruene, O. E. Isaac, and B. Nkoi, “The Inhibitive Effect of Breadfruit Leaf Extracton Mild Steel Corrosion,” Journal of Newviews in Engineering and Technology, vol. 3, pp. 34-43, 2021.

Y. B. Waidi, B. Nkoi, R. K. C. Amadi and A. A. Luke, “Determination of the Effect of Newbouldia leavis Leaf Extract on the Corrosion of Mild Steel in Sulphuric Acid,” Journal of Newviews in Engineering and Technology, vol. 2, pp. 9-16, 2020.

O. O. Fadare, A. E. Okoronkwo and E. F. Olasehinde, “Assessment of Anti – corrosion Potentials of Extract of Fiscus asperifolia – Miq (Moraceae) on Mild Steel in Acidic Medium,” African Journal of Pure and Applied Chemistry, vol. 10, pp. 8-22, 2016.

J. T. Nwabanne, V. N. Okafor and L. O. Chima, “Adsorption Mechanism and Synergistic Inhibitive Effect of Telfairia occidentalis for the Corrosion of Mild Steel in Hydrochloric Acid,” Journal of Engineering and Applied Sciences, vol. 3, pp. 92-100, 2011.

R. Saratha, S. V. Priya, and P. Thilagavathy, “ Investigation of Citrus aurantiltolia Leaves Extract as a Corrosion Inhibitor for Mild Steel in 1 M HCl,” Electronic Journal of Chemistry, vol. 6, pp. 785-795, 2009.

H. Adamu and R. O. Ngwu, “Phytochemical Screening and Antibacterial Activities of Hibiscus sabdariffa L leaf Extracts,” Nigerian Journal of Chemical Research, vol. 20, pp. 46-52, 2015.

C. N. Okereke, F. C. Iroka and M. O. Chukwuma, “Phytochemical Analysis and Medicinal Uses of Hibiscus sabdariffa,” International Journal of Herbal Medicine, vol. 2, pp. 16-19, 2015.

T. O. Alaga, M. O. Edema, A. O. Atayese and M. O. Bankole, “Phytochemical and Invitro Anti-bacterial Properties of Hibiscus sabdariffa L (Roselle) Juice,” Journal of Medical Plants Research, vol. 8, pp. 339-344, 2014.

E. E. Oguzie, B. N. Okolue, C. E. Ogukwe, A. I. Omchukwu, and C. Unaegbum, “Studies on the Inhibitive Action of Methylene Blue Dye on Aluminium Corrosion in KOH Solution,” Journal of Corrosion Science and Technology, vol. 1, pp. 88-91, 2004.

I. M. Mejeha, A. A. Uroh, K. B. Okeoma and G. A. Alozie, “The Inhibitor Effect of Solomon Melongena L. Leaf Extracts on the Corrosion of Aluminium in Tetraoxosulphate (VI) Acid,” African Journal of Pure and Applied Chemistry, vol. 4, pp. 158-165, 2010.

B. D. B. Tiu and R. C.Advincula, “Polymeric corrosion inhibitors for the oil and gas industry: design principles and mechanism,” Reactive and Functional Polymers, vol. 95, pp. 25-45, 2015.

M. G. Fontana, Corrosion Engineering (3rd Edition), New York, McGraw Hill Book Co, 1987.

S. A. Umoren, T. B. Obot, E. E. Ebenso and P. C. Okafor, “Eco-friendly Inhibitor from Naturally Occurring Exudate Gums for Aluminium Corrosion Inhibition in Acidic Medium,” Portugaliae Electrochemical Acta, vol. 26, pp.267-282, 2008

J. Sheng, “Effect of Simulated Pitting Corrosion on the Tensile Properties of Steel,” Construction and Building Materials, vol. 131, pp. 90–100, 2017

L.B. Molina-Ocampo, M. G. Valladares-Cisneros and J. G. Gonzalez-Rodriguez, “Using Hibiscus sabdariffa as Corrosion Inhibitor for Al in 0.5 M H2SO4,” International Journal of Electrochemical Science, vol. 10, pp.388-403, 2015

C. E. Ogukwe, C. O. Akalezi, M. A. Chidiebere, K. L. Oguzie, Z. O. Iheabunike, and E. E. Oguzie, “ Corrosion Inhibition and Adsorption of Anthocleista djalonesis Leaf Extract on the Acid Corrosion of Mild Steel,” Portugaliae Electrochemica Acta, vol. 30, pp. 189 – 202, 2012.

E. E. Oguzie, “Adsorption and Corrosion Inhibitive Properties of Azardirachta indica in Acid Solutions, Pigment and Resin Technology,” vol. 25 pp. 67 – 76, 2006.

Y. L. Shuaib – Babata, Y. O. Busari, R. A. Yahya and J. M. Abdul, “Corrosion Inhibition of AISI 1007 Steel in Hydrochloric Acid Using Cucumis sativus (Cucumber) Extracts as Green Inhibitor,” Acta Technica Corviniensis, vol. 4, pp. 153 – 161, 2018.

O. Babatunde, S. O. Ogunrinde and A. A. Adeyemi, “Corrosion Mechanism of Mild Steel in Acidic Solution and Adsorption Thermodynamics in the Presence of Water Hyacinth Extract,” Journal of Material Sciences and Engineering, vol. 8, pp. 1 – 8, 2019.

V. O. Izionworu, E. E. Oguzie and O. I. Arukalam, “Thermodynamic and Adsorption Evaluation of Codiaeum Variegatum Brilliantissima – Zanzibar as Inhibitor of Mild Steel Corrosion in 1 M HCl,” Journal of Newviews in Engineering and Technology, vol. 2, pp. 1 – 13, 2020.

I. E. Uwah, P. C. Okafor and V. E. Ebiekpe, “ Inhibitive Action of Ethanol Extracts from Nauclea latifolia on the Corrosion of Mild Steel in H2SO4 Solutions and Their Adsorption Characteristics,” Arabian Journal of Chemistry, vol. 6, pp. 285 – 293, 2010.

V. M. Abbasov, H. M. Abd El Lateef, L. T. Aliyeva, E. E. Qasimov, I. T. Ismayilov and M. M. Khalaf, “A Study of the Corrosion Inhibition of Mild Steel C1018 in CO2 – Saturated Brine using Some Novel Surfactants Based on Corn Oil,” Egyptain Journal of Petroleum, vol. 22, pp. 451 – 470, 2013.

F. E. Abeng, U. J. Ekpe, A. I. Ikeuba, B. U. Ugi and P. J. Nna, “ Inhibitive Action of Alkaloids and Non – Alkaloid fractions of the ethanoic extracts of Phyllanthus Amarus on the corrosion of mild steel in HCl solution,” Global Journal of Pure and Applied Sciences, vol. 19, pp. 107 – 117, 2013.

E. A. Noor, “ Potential Aqueous Extract of Hibiscus sabdariffa Leaves for Inhibiting the Corrosion of Aluminum in Alkaline Solutions,” Journal of Applied Electrochemistry, vol. 39, pp. 1475 – 1465, 2009.

N. Chaubey, D. K. Yadav, V. K. Singh, V. K and M. A. Quraishi, “A Comparative Study of Leaves Extracts for Corrosion Inhibition Effect on Aluminum Alloy in Alkaline Medium,” Ains Shams Engineering Journal, vol.8, pp.673-682, 2017.

S. Paul and I. Koley, “Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor,” Journal of Bio and Tribo Corrosion, vol. 2, pp. 1-9, 2016.

A. El – Awady, B. A. Abd – Nabey and S. G. Aziz, Thermodynamic and Kinetic factors in Chloride ion Pitting and Nitrogen Donor Ligands Inhibition of Aluminium Metal Corrosion in Aggressive Acid Media, Journal of the Chemical Society; Faraday Transactions, vol. 89, pp. 795 – 802, 1992.

I. E. Uwah, B. U. Ugi, A. I. Ikeuba and U. B. Essien, “Costus Afer Leave Extract as Nontoxic Corrosion Inhibitor for Mild Steel in H2SO4,” Global Journal of Pure and Applied Sciences, vol.19, pp. 119 -127, 2013.

A. Machrouhi, M. Farnane, A. Elhalil, M. Abdennouri, H. Tounsadi and N. Barka, “Heavy Metals Biosorption by Thapsia Transtagana Stems Powder, Kinetics, Equilibrium and Thermodynamics,” Moroccan Journal of Chemistry, vol. 7, pp. 98 – 110, 2019.

O. O. Ogunleye, A. O. Arinkoola, O. A. Eletta, O. O. Agbede, Y. A. Osho, A. F. Morakinyo and J. O. Hamed, “Green Corrosion Inhibition and Adsorption Characteristics of Luffa cylindrical leaf Extract on Mild Steel in Hydrochloric Acid Environment,” Heliyon, vol. 6, 1-12, 2020.

article IJEAP : Corrosion inhibition potentials of Roselle (Hibiscus sabdariffa) in tetraoxosulphate (VI) acid solution

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Published

2022-09-25

How to Cite

[1]
E. Elachi, A. . Justine, M. . Paul, K. . D. Yusuf, and A. . B. Madugu, “Corrosion inhibition potentials of Roselle (Hibiscus sabdariffa) in tetraoxosulphate (VI) acid solution”, International Journal of Engineering and Applied Physics, vol. 2, no. 3, pp. 524–534, Sep. 2022.

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