Preparation and Study of the Physical Properties of CdSe Films Deposited by a Chemical Bath Method and Exposed to Neutron Irradiation
Effect of neutron irradiation on a CdSe film prepared
Keywords:
CdSe thin film, CBD method, energy gap, neutron source, neutron flux, particle size, spectrophotometerAbstract
This study deals with the preparation of CdSe films using two sources of cadmium, (CdCl2) and (CdSO4), and studying the effect of neutron irradiation on their optical and structural properties. Using CBD method, the films were prepared on glass substrates at a temperature of 50 •C, with a deposition time of 3 hours. These films were exposed to the neutron beam from the radioactive source (Am241-Be10) with a neutron flux (3*105 n/cm2.s) and an energy of 5 MeV for 7 days. It was noted that neutron irradiation has a significant effect on the physical properties of the films. Using a UV-V spectrophotometer, the optical properties of the films were studied. It was found that the absorption coefficient (?) and the energy gap increase with irradiation, and from the following XRD, FESEM and EDX measurements, the shape and structure of the prepared and irradiated films were determined. X-ray measurements have shown that there are preferred directions for grain growth [111], [220], and [311]. It was also observed that the grain size increases, while the relative density decreases with irradiation. As for FESEM measurement, it was noted that the surface shape of the films is greatly affected when exposed to neutron radiation.
Downloads
References
AH Johnston, Radiation Damage of Electronic and Optoelectronic Devices in Space. Jet Propulsion Laboratory. 4800 Oak Grove Drive Pasadena, California (USA). 2000.
C Narula, and RP Chauhan. High Dose Gamma Ray Exposure Effect on the Properties of CdSe Nanowires. Radiation physics and Chemistry. 2017.
CV Hernàndez, VC Lara, JE Vallejo, JF Jurado, and O Giraldo. XPS, SEM, and XRD investigations of CdSe films prepared by chemical bath deposition. Phy. Stat. Sol. (b). 2005, vol. 242(9): 1897-1901.
DDO Eya. Optical Properties and Applications of Cadmium Selenide (CdSe) Thin Films Prepared by Chemical Bath Deposition Technique. Pacific Journal of Science and Technology. 2006, 7,(1):64-68.
DH Al Refaei, LA Najam, and LM Al Taan.The Effect of Neutron Irradiation on Optical, Structural and Morphological Properties of Cadmium Selenide Thin Films. J. Rad. Nucl. Appl. 2021, 6, No. 3, 207-216.
DH Al Refaei, LM Al Taan , and L A Najam.The Effect of ?-Particles on Structural, Optical and Morphological Properties for Cadmium Selenide Thin Films. Journal of Physics. 2021, 1973 (012155).
E Lifshitz, I Dag, I Litvin, G Hodes, S Gorer, R Reisfeld, M Zelner, and H Minti. Optical properties of CdSe nanoparticle films prepared by chemical deposition and Sol-gel methods. Chemical Physics Letters. 1998, Vol.288: 188-196.
?A Kariper, Ö BA?LAYAN, and F GÖDE. Fabrication and Optical Characterization of CdSe Thin Films Grown by Chemical Bath Deposition. Acta Physica Polonica A. 2015, vol. 128(2-B): 219-221.
JP Mitchell, and DK Wilson. A summary of surface effects of radiation on semiconductor devices. The Bell system technical J.1966, No.1, 1(USA).
JS Blakmore. Solid State Physics. 2th Ed., Cambridge Press, London.1986.
K Boubaker. A physical explanation to the controversial Urbach tailing universality. The Eur. Phys. J. Plus. 2011, 126(10).
K Girija, S Thirumalairajan, SM Mohan, and J Chandrasekaran. Structural and optical characteristics of CdSe thin films prepared by chemical bath deposition technique. Iraqi Journal of Applied Physics Letters. 2009, 2(4): 21-24.
KL Chopra. Thin film phenomena. Mc Graw-Hill, New york. 1996.
M Agarwal. High Energy Radiation Effects in Semiconductor Devices used in Space Application. Bachelor of Technology, National Institute of Technology Rourkel, India. 2011.
MA Ibrahim. Design Neutrons Protection shielding by using composite materials. Master Thesis. 2019.
MA Khalil. Nuclear Physics. 1996, pp 132-149.
N Gopakumar, PS Anjana, and PK Vidyadharan Pillai. Chemical bath deposition and characterization of CdSe thin films for optoelectronic application. J. Mater Sci. 2010, 45:6653- 6656.
NST N, PH L, and G R. Synthesis of CdSe thin film by chemical bath deposition and characterization. (IJESIT). 2017, Vol: 6, Issue 1.
P Mahawela, S Jeedigunta, S Vakkalanka, CS Ferekides, and DL Morel. Transparent high-performance CdSe thin-film solar cells. Thin Solid Films. 2005, vol. 480-481, pp. 466-470.
RI Chowdhury, M S Islam, F Sabeth, G Mustafa, SFU Frahad, DK Saha,..., and ABMO Islam. Characterization of Electrodeposited Cadmium Selenide thin films. Dhaka Univ. J. Sci. 2012, 60(1):137-140.
S Ahmad, MS Khan, K Asokan, and M Zulfequar. Effect of Gamma Irradiation on the Structural and Optical Properties of Thin Films of a-CdSe. International Journal for Light and Electron Optics. 2015, 126(23): 3501-3505.
S Erat, H Metin, and M Ari. Influence of the annealing in nitrogen atmosphere on the XRD, EDX, SEM, and electrical properties of chemical bath deposited CdSe thin films. Materials Chemistry and Physics. 2008, 111: 114-120.
SH Park, and JO Kang. Basics of particle therapy I: physics. Radiation Oncology Journal. 2011, 29(3): 135-146.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Laith Najam, Laith M. Al Taan , Duha Hashim Al Refaei
This work is licensed under a Creative Commons Attribution 4.0 International License.
Copyright on any article in the International Journal of Engineering and Applied Physics is retained by the author(s) under the Creative Commons license, which permits unrestricted use, distribution, and reproduction provided the original work is properly cited.
License agreement
Authors grant IJEAP a license to publish the article and identify IJEAP as the original publisher.
Authors also grant any third party the right to use, distribute and reproduce the article in any medium, provided the original work is properly cited.
Most read articles by the same author(s)
- Zainab Hammo, Laith Najam, Laith Al_Taan, Gamma Radiation Effects on The Performance of The CdSe Thin Film for Photodetector Application , International Journal of Engineering and Applied Physics: Vol. 4 No. 2: May 2024
- Zainab Mowafaq Marie, Laith Najam, Taha Yaseen Wais, Berivan F. Namq, Radionuclides Distribution in Al-Qayyarah Oil Wells and refinery in Nineveh Government, Iraq , International Journal of Engineering and Applied Physics: Vol. 4 No. 3: September 2024